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Neodymium(III) chloride
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Neodymium(III) chloride : ウィキペディア英語版
Neodymium(III) chloride

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Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).
== Appearance ==

NdCl3 is a mauve colored hygroscopic solid whose color changes to purple upon absorption of atmospheric water. The resulting hydrate, like many other neodymium salts, has the interesting property that it appears different colors under fluorescent light- In the chloride's case, light yellow (see picture). The color difference is likely due to the charge transfer converting the Nd3+ ions into the Nd2+ state; the orange absorption band of Nd3+ decreases and the green Nd2+ absorption increases producing the yellowish color.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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